Non-Covalent Pi-System Interactions

Elizabeth Bess University of Utah Noncovalent interactions with Pi systems Overview Noncovalent interactions are the underpinnings of chemical selectivity molecular recognition and supramolecular molecules tertiary structure eg enzymes and DNA These throughspace rather than throughbond interactions arise from attractions between oppositely and fully or partially charged species One such class of noncovalent interactions are the intermolecular interactions of pi systems with other pi systems or charged species

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